It is possible that a harmonisation is introduced through an amendment to the CLP Regulation. The quality and correctness of the information submitted to ECHA remains the responsibility of the data submitter. 0000003675 00000 n Indiquer NC8=29171200, Programme International sur la Sécurité des Substances Chimiques, A post-Kyoto partner: considering the stratospheric ozone regime as a tool to manage nitrous oxide, https://fr.wikipedia.org/w/index.php?title=Acide_adipique&oldid=161197749, Pages avec des arguments non numériques dans formatnum, Infobox Chimie avec données 67/548/EEC redondantes à supprimer, licence Creative Commons attribution, partage dans les mêmes conditions, comment citer les auteurs et mentionner la licence, Représentations planes et 3D de l'acide adipique. Substances for which classification and labelling data have been notified to ECHA by manufacturers or importers. Release to the environment of this substance can occur from industrial use: manufacturing of the substance. Earn Transferable Credit & Get your Degree. The two comonomers are first reacted to form a salt. L'acide adipique ou acide 1,6-hexanedioïque est un diacide carboxylique aliphatique. Select a subject to preview related courses: Although less common than the other method we just mentioned, adipic acid can also be made by the carbonylation of butadiene. 0000008348 00000 n Production of PBAT involves 1,4-butanediol with terephthalic (dimethyl terephthalate (DMT)) and, https://en.wikipedia.org/wiki/polybutyrate. The InfoCard summarises the non-confidential data of a substance held in the databases of the European Chemicals Agency (ECHA). Silver Carbonate: Chemical Formula & Solubility, Over 83,000 lessons in all major subjects, {{courseNav.course.mDynamicIntFields.lessonCount}}, What is Acrylic Acid? Nylon 66 is produced by the condensation reaction of hexamethylenediamine and adipic acid. The potential degradability of the synthesized copolyamides was confirmed by various biodegradability experiments, such as alkali hydrolysis, microbial-bacterial attack (burial in soil), and enzymatic hydrolysis. 0000001445 00000 n These fibers can be beneficially used for tire cord, sewing thread, filters, and felts. EU. Did you know… We have over 220 college This mobility promotes crystallization, as reflected by the high Xc values. Release to the environment of this substance can occur from industrial use: for thermoplastic manufacture, as an intermediate step in further manufacturing of another substance (use of intermediates), as processing aid, as processing aid and formulation of mixtures. Caprolactam is a cyclic organic compound with the formula: Caprolactam is a colorless solid that melts at around 70°C [54]. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). nécessaire]. flashcard set{{course.flashcardSetCoun > 1 ? Adipic acid isn't its only name, but it's the one most commonly used. Substances listed in the EINECS, ELINCS, or NLP inventories. Structure of Adipic Acid. Adipic acid or hexanedioic acid is the organic compound with the formula (CH2)4(COOH)2. 66/2010/EC, L 27/1, 30 Jan 2010 (T. 3 of Anx VI to CLP; Candidate List of SVHCs), EU. In one industrial process, a mixture of cyclohexanone and cyclohexanol is oxidized with nitric acid in a multistep pathway. {{courseNav.course.topics.length}} chapters | Nylon 46 resin is made by reacting 1,4-diaminobutane with adipic acid. The novel copolyamides, based on adipic acid (AA), 1.6-hexane diamine (1.6-HD), isophorone diamine (IPD), bis(para-aminocyclohexyl)-methane (PACM-20), and various α-amino acids (l-tyrosine, proline, alanine, glycine, glutamic acid), were synthesized by a two-stage melt polycondensation (100°C and 250°C for 1 and 2 h, respectively). There are different ways to synthesize caprolactam, with the increasing significance of Nylon 6 as a polymer; various routes to industrial production of caprolactam have been developed. L'oxydation du mélange cyclohexanol-cyclohexanone par l'acide nitrique, conduit à une coproduction d'acide adipique et de protoxyde d'azote gazeux (N₂O), dans la proportion d'environ 0,3 T N₂O pour 1T d'acide adipique. Alternative feedstock in the synthesis of adipic acid is D glucose, which is converted to cis-muconic acid using E. coli, which is further hydrogenated to adipic acid using hydrogen gas. ECHA has no public registered data indicating whether or into which articles the substance might have been processed. %PDF-1.3 %���� Other release to the environment of this substance is likely to occur from: outdoor use as reactive substance. Un article de Wikipédia, l'encyclopédie libre. The initial random chain scissions result in a decrease of the degree of entanglement, thus facilitating and even considerably promoting the mobility of nondegradable chain segments in these regions. The adipic acid is carefully purified by subjection to such processes as steam distillation and crystallisation. Nylon 66 also has a higher heat deflection temperature and slightly lower moisture absorption than nylon 6. This substance is used in the following products: washing & cleaning products. However, following the dissolution of the amorphous regions, the degradation proceeds to the crystalline regions. You can test out of the The molar mass of copolyamides was not substantially affected when the copolyamides were buried in soil. Information on applicable regulatory frameworks is also automatically generated and may not be complete or up to date. Please be aware there may be intermittent unavailability while work in ongoing. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. URL: https://www.sciencedirect.com/science/article/pii/B9780444640000000123, URL: https://www.sciencedirect.com/science/article/pii/B9780123725325500109, URL: https://www.sciencedirect.com/science/article/pii/B9780081020418000081, URL: https://www.sciencedirect.com/science/article/pii/B9780750641326500590, URL: https://www.sciencedirect.com/science/article/pii/B978012804190100001X, URL: https://www.sciencedirect.com/science/article/pii/B9781455731121000144, URL: https://www.sciencedirect.com/science/article/pii/B9780081012727000122, URL: https://www.sciencedirect.com/science/article/pii/B9781455732012000070, URL: https://www.sciencedirect.com/science/article/pii/B9780323358859000023, URL: https://www.sciencedirect.com/science/article/pii/B9780128131404000169, Pyrolysis of Organic Molecules (Second Edition), Traditional feedstock for the synthesis of, Chemical intermediates, such as catechol and, Waste Management for Polymers in Food Packaging Industries, Arvanitoyannis et al., 1993, 1994a,b,c,d, 1995a,b,c,d,e,f,g, The chemistry, manufacture, and tensile behavior of polyamide fibers, Handbook of Properties of Textile and Technical Fibres (Second Edition), Plastics in Medical Devices (Second Edition), ). By continuing you agree to the use of cookies. Details of dossier compliance checks and testing proposal evaluation. Unsere Website wird von Internet Explorer 7 (und älteren Versionen) nicht uneingeschränkt unterstützt. Il est utilisé principalement pour la fabrication du nylon, et plus généralement pour la synthèse des polyamides. just create an account. Z = 2 [4]. We are going to start off our synthesis discussion by seeing how adipic acid can be made on a small laboratory scale. In step 2, both DMT and 1,4-butanediol at 160°C produce polyesters. The reaction usually requires harsh conditions and unwanted side-products are often formed, which is why this method is not as favored as the synthesis from KA oil. Wie werden Mitteilungen des nachgeschalteten Anwenders eingereicht? C'est également un additif alimentaire (E355) utilisé pour acidifier des boissons non alcoolisées ou contrôler lacidité des cosmétiques. This substance is used in the following areas: formulation of mixtures and/or re-packaging and municipal supply (e.g. If generated, an InChI string will also be generated and made available for searching. Structure, properties, spectra, suppliers and links for: Adipic acid dihydrazide, 1071-93-8. The CLP Regulation uses the UN Global Harmonised System (GHS) and European Union Specific Hazard Statements (EUH). Note that this list is not exhaustive. The precautionary measures and guidance on safe use are as submitted to ECHA by registrants under the REACH Regulation. The reactions leading to cyclopentanone and further to 2-cyclopentylidene-cyclopentan-2-one are shown below: Substituted adipic and pimelic acids can be used for the preparation of ketones using reactions of the type (12.2.18). machine wash liquids/detergents, automotive care products, paints and coating or adhesives, fragrances and air fresheners). Union List of Authorized Substances: Annex I, Plastics Food Contact Regulation 10/2011/EU, as amended by Regulation 2019/1338/EU, 9 Aug 2019, EU.