Synthesis and Reactivity of Cyclic 4-π Electron Ylides: Non-Antiaromatic Inorganic Ring Systems. Keisham Sarjit Singh, Kevin A. Kreisel, Glenn P. A. Yap, Mohan Rao Kollipara. Yeon Joo Jung, Yu Mi Chang, Ji Hee Lee, Cheol Min Yoon. D. J. Mergott, S. A. Frank, W. R. Roush. Xuejun Zhang, Hongyan Li, Lingfeng You, Yu Tang, Richard P. Hsung. Transformations on 2,3,4,5-tetrahydrobenzo[ Valerii P. Vetchinov, Elena B. Nikolaenkova, Victor I. Mamatyuk, Victor P. Krivopalov. A facile reduction of aromatic nitro compounds to aromatic amines by samarium and iodine. 2  2] cycloaddition of activated nitrile and alkynes to indenyl ruthenium azido complexes: crystal structures of [( Meinolf Lange, Anne Lise Pettersen, Kjell Undheim. (CO) The acyl azide is usually made from the reaction of acid chlorides or anydrides with sodium azide or trimethylsilyl azide. H Covalent amino-functionalisation of single-wall carbon nanotubes. Synthesis of Glycosylamines from Glycosyl Isothiocyanates and Bis(tributyltin) Oxide. Silvia Díez-González, Andrea Correa, Luigi Cavallo, Steven P. Nolan. The generation and rearrangement of a conformationally restricted secondary aminodiazonium ion.. Dmitry E. Bochkariov, Alexander A. Kogon. Ring Closure of 4-Azido-3-formyl-(or Acetyl-)2-pyridones to Isoxazolo[4,3-c]pyridones. Construction of Highly Functionalized Bridged Isoquinoline Synthons. Please reconnect. Panayota Bitha, Timothy W. Strohmeyer, Zhong Li, Yang-I Lin. Preparation of Polyfuntional Acyl Azides.. ChemInform 2007 , 38 (48) DOI: 10.1002/chin.200748035. [21][22] -H Keisham Sarjit Singh, Kevin A. Kreisel, Glenn P.A. Simon Y.M. A Novel, Chemoselective and Efficient Production of Amines from Azides Using ZrCl Heating the azide in ethanol yields the ethyl carbamate via the Curtius rearrangement. Carbocation lifetimes and entropy of water addition to carbocations dependent on their stability. F. Palacios, D. Aparicio, J. M. de los Santos, I. Perez de Heredia, G. Rubiales. )-quinolones. jo070162esi20070413_113128.pdf (653.07 kb), http://pubs.acs.org/page/copyright/permissions.html, https://doi.org/10.1016/j.jaap.2017.01.001, https://doi.org/10.1007/978-981-10-2813-7_5, https://doi.org/10.1016/j.bmc.2016.08.044, https://doi.org/10.1107/S241431461601155X, https://doi.org/10.1016/j.tetlet.2016.04.098, https://doi.org/10.1016/j.tetlet.2015.11.038, https://doi.org/10.1007/s00706-014-1408-1, https://doi.org/10.1016/j.cclet.2012.01.031, https://doi.org/10.1002/0471238961.azidbras.a01, https://doi.org/10.1016/j.tetlet.2011.07.057, https://doi.org/10.1080/00397911.2010.505698, https://doi.org/10.1002/9783527637737.ch12, https://doi.org/10.1016/j.tetlet.2010.04.002, https://doi.org/10.1016/S0959-6380(09)70012-1, https://doi.org/10.1016/B978-008044992-0.00501-0. 2 Stanislaw Ryng University of Medicine, Faculty of Pharmacy Department Organic Chemistry , 50-137 Wroclaw, 9, Grodzka, Poland & Tadeusz Glowiak Institute of Chemistry, University of Wroclaw , 50-383 Wroclaw, 14 F. Joliot-Curie, Poland . Synthesis and photolysis of protected d-hex-2-ulopyranosyl azides. Photochemistry of mesoionic compounds. Giselle Cerchiaro, Ana M. Da Costa Ferreira, Aline B. Teixeira, Hugo M. Magalhães, Anna C. Cunha, Vitor F. Ferreira, Leonardo S. Santos, Marcos N. Eberlin, Janet M.S. Anna E. Täubl, Klaus Langhans, Thomas Kappe, Wolfgang Stadlbauer. Stefan Bräse, Carmen Gil, Kerstin Knepper, Viktor Zimmermann. Your Mendeley pairing has expired. P Xiao-Qiang Li, Wei-Kun Wang, Chi Zhang. Direct Synthesis of Acyl Azides from Carboxylic Acids Using 2-Azido-1,3-dimethylimidazolinium Chloride. [3] Several reviews have been published. -hemipinate”: First example of a reaction involving a concomitant ring expansion and ring extrusion. The substituent effect upon the iminophosphorane X3PNH for X=F, Cl, Br, H, CH3, C6H5, CH3CH2, and (CH3)3C. the Altmetric Attention Score and how the score is calculated. They can also be synthesized from various carboxylic acids and sodium azide in presence of triphenylphosphine and trichloroacetonitrile catalysts in excellent yields at mild conditions. Alternatively, the acyl azide can be formed by the direct reaction of a carboxylic acid with diphenylphosphoryl azide (DPPA). Unsworth et al.’s protecting group-free total synthesis of dievodiamine utilizes the Curtius rearrangement in the first step of the synthesis, catalyzed by boron trifluoride.